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- 详细信息
- 文献和实验
- 技术资料
- 英文名:
tert-butyl(8aS)-3-oxo-5,6,8,8a-tetrahydro-1H-1,3oxazolo3,4-apyrazine-7-carboxylate
- 库存:
999
- 供应商:
智溯科ZSK
- CAS号:
958635-18-2
- 规格:
10mg/100mg/8893mg
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文献和实验The dipeptidic dihydroxyethylene isostere (27, 3R , 4R , 5S )-5-tert -butyloxy-carbonylamino-3,4-dihydroxy-2-isopropyl-3,4-O,O -isoprop-ylidene-6-cyclohexyl-hexanoic acid, 15 , is a representative building block of an important class
and lack sensitivity. GC methods based on the conversion into trimethylsilyl (4 ,5 ), neopentylidine (6 ), and N-trifluoroacetyl n -butyl ester (7 ) derivatives lack sensitivity, gives a tailing peak and requires anhydrous derivatization conditions
Natural Product Chemistry in Action: The Synthesis of Melatonin Metabolites K1 and K2
melatonin, the kynurenamines N1-acetyl-N2 -formyl-5-methoxykynurenine (K1 ) and N -acetyl-5-methoxykynurenamine (K2 ). The four key synthetic transformations involve (a) conversion of 4-methoxy aniline into the tert -butyl (4-methoxyphenyl)carbamate, (b
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