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文献和实验Use of Chiral Crown Ethers in Capillary Electrophoresis
. (11 ) transferred this basic principle to capillary electrophoresis (CE) using (+)−18-crown-6-tetracarboxylic acid (Fig. 1 ) as a chiral selector added to the electrolyte for the chiral separation of amino acids. This crown ether was shown
4 -2 3 7 3 . 25. L awrence, R. J. and P ik aard , C. S. (2 0 0 3 ) T ran sgene-in d uced RNA in terferen ce ： a strategy for overcoming gene redundancy in polyploids to generate loss-of-function m utations. Plant J. 3 6 , 11 4 -121
titration calorimetry (ITC) data for titration of 5.7 mM 18‐crown‐6 ether with 5‐µL injections of 103 mM barium. (A ) Raw power (µcal/sec) versus time tracing. At each injection an exothermic “spike” is seen. The area under each spike is proportional
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