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- 详细信息
- 文献和实验
- 技术资料
- 保存条件:
充氩
- 英文名:
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
- 库存:
现货
- 供应商:
上海阿拉丁生化科技股份有限公司
- CAS号:
100165-88-6
- 规格:
S115619-5g/S115619-250mg/S115619-1g/S115619-25g
| 规格: | S115619-5g | 产品价格: | ¥596.9 |
|---|---|---|---|
| 规格: | S115619-250mg | 产品价格: | ¥37.9 |
| 规格: | S115619-1g | 产品价格: | ¥176.9 |
| 规格: | S115619-25g | 产品价格: | ¥3016.9 |
(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO3, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides.It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.
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文献和实验Enzymatic Synthesis of (S)-Phenylalanine and Related (S)-Amino Acids by Phenylalanine Dehydrogenase
substituents in the reductive amination reaction. Optically pure (S)-phe and other (S)-amino acids are quantitatively synthesized from their oxo-analogs using PheDH, with a regeneration of NADH by formate dehydrogenase from Candida boidinii No. 2201. Acetone
have led to the conclusion that CYP2C19 is a major P450 responsible for (S)-mephenytoin 4’-hydroxylation activity in human liver microsomes (1 , 2 ). This is supported by the finding that cDNA-expressed CYP2C19 has a 50-to lOO-fold greater turnover number
A reverse-phase, high-performance liquid chromatography method is described for the quantification of 4′-hydroxymephenytoin formed enzymatically from 14 C-labeled (S )-mephenytoin following incubation with cDNA-expressed CYP2C19 or human
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